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- W1569235673 abstract "The next step in our systematic examination of the radical cationinitiated dimerization of plant monomers from the D{sub 6}-C{sub 3} pool of shikimic acid metabolites was to study the dimerization of cinnamic acid and its derivatives. In order to do this we needed a radical cation initiator that has a reduction potential greater than that of BAHA (E{sub red} = 1.30 volts), since the electron-withdrawing carboxylate functional group of cinnamates renders them inert to oxidation with BAHA. This problem was solved with the observation that DBAHA tris-(2,4-dibromophenyl)aminium hexachloroantimonate, E{sub red} = 1.74 volts, intiated the radical cation dimerization of methyl 3,4-dimethoxycinnamate." @default.
- W1569235673 created "2016-06-24" @default.
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- W1569235673 date "1990-01-01" @default.
- W1569235673 modified "2023-09-27" @default.
- W1569235673 title "Coalification by clay-catalyzed oligomerization of plant monomers" @default.
- W1569235673 doi "https://doi.org/10.2172/6203204" @default.
- W1569235673 hasPublicationYear "1990" @default.
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