FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W156923741> ?p ?o ?g. }

• W156923741 abstract "In order to obtain a non-corrosive fuel gas (syngas), which is derived from coal by Integrated Gasification Combined Cycle (IGCC) technology and used in power plants, hydrogen sulfide (H2S), which is generated during the gasification process due to sulfur contained in coal, should be removed to protect instruments, especially turbines, from corrosion. To improve H2S removal efficiency and develop excellent regenerative catalyst, we conducted the following research. Simulated syngas was introduced into a fixed-bed quartz reactor where carbonaceous sorbents (which are excellent sorbents and have lower price) were positioned to capture H2S. Tail gases from the outlet of the reactor including H2S, COS, and SO2 were continuously monitored by a residual gas analyzer (or mass spectrometer) to determine the capacity of H2S uptake and selectivity of adsorption/oxidation by different sorbents. Carbonaceous materials including carbon black, graphite and activated carbon fibers (ACFs) were compared for the application in desulfurization. Rare earth metal oxides (La2O3 and CeO2) were investigated and used to modify ACFs due to their potential to effectively remove H2S and multicycle regenerative ability. Water vapor and temperature effects on H2S removal were studied. Functional groups on carbonaceous materials were determined and the mechanism of the promotion of H2S uptake by basic functional groups was proposed. Through the determination of activation energy of desorption of sulfur species from sulfided sorbents, it is concluded that chemisorption is the dominant mechanism at higher sulfurization temperature, while physisorption is the controlling process at lower temperature. At the temperature ranging from 110 to 170 iaC, the best H2S-uptake capacity was obtained because chemisorption and physisorption are both present and water film on the surface of sorbents is ideally maintained. The observation of sulfurization and regeneration of sorbents and by-products related that nitrogen could only remove physically adsorbed H2S and hydroxide could, to some extent, restrain the formation of by-products (the reaction between COS or SO2 and hydroxide). ACFs modified by metal compounds showed excellent H2S-uptake capacity (up to 35 mg H2S/g Sorbent) in the 1st cycle but the capacity in the subsequent cycles were much lower than the 1st cycle because regeneration gas (nitrogen) could not recover the chemically adsorbed sulfur species." @default.
• W156923741 created "2016-06-24" @default.
• W156923741 creator A5013450626 @default.
• W156923741 date "2008-06-09" @default.
• W156923741 modified "2023-09-24" @default.
• W156923741 title "SELECTIVE CATALYTIC OXIDATION OF HYDROGEN SULFIDE FROM SYNGAS" @default.
• W156923741 cites W190836089 @default.
• W156923741 cites W1917322655 @default.
• W156923741 cites W1968129529 @default.
• W156923741 cites W1971315572 @default.
• W156923741 cites W1972737400 @default.
• W156923741 cites W1973032910 @default.
• W156923741 cites W1977234056 @default.
• W156923741 cites W1977622737 @default.
• W156923741 cites W1979393006 @default.
• W156923741 cites W1980996287 @default.
• W156923741 cites W1986688428 @default.
• W156923741 cites W1989674502 @default.
• W156923741 cites W1990352955 @default.
• W156923741 cites W1992553622 @default.
• W156923741 cites W1993894077 @default.
• W156923741 cites W1995623410 @default.
• W156923741 cites W1996635175 @default.
• W156923741 cites W1997033030 @default.
• W156923741 cites W1998941691 @default.
• W156923741 cites W2000176065 @default.
• W156923741 cites W2003030769 @default.
• W156923741 cites W2007778464 @default.
• W156923741 cites W2008027661 @default.
• W156923741 cites W2011862887 @default.
• W156923741 cites W2015948162 @default.
• W156923741 cites W2017682181 @default.
• W156923741 cites W2027088599 @default.
• W156923741 cites W2028678615 @default.
• W156923741 cites W203392614 @default.
• W156923741 cites W2036221256 @default.
• W156923741 cites W2036259246 @default.
• W156923741 cites W2036726466 @default.
• W156923741 cites W2037880146 @default.
• W156923741 cites W2045548761 @default.
• W156923741 cites W2046564020 @default.
• W156923741 cites W2047246435 @default.
• W156923741 cites W2048267788 @default.
• W156923741 cites W2049421278 @default.
• W156923741 cites W2050482019 @default.
• W156923741 cites W2051315312 @default.
• W156923741 cites W2054256971 @default.
• W156923741 cites W2054532001 @default.
• W156923741 cites W2058651598 @default.
• W156923741 cites W2065046995 @default.
• W156923741 cites W2068726563 @default.
• W156923741 cites W2068990400 @default.
• W156923741 cites W2077208993 @default.
• W156923741 cites W2082845533 @default.
• W156923741 cites W2085830302 @default.
• W156923741 cites W2087392483 @default.
• W156923741 cites W2089810274 @default.
• W156923741 cites W2119957093 @default.
• W156923741 cites W2121885075 @default.
• W156923741 cites W2164455129 @default.
• W156923741 cites W2167773819 @default.
• W156923741 cites W2192267764 @default.
• W156923741 cites W2359804808 @default.
• W156923741 cites W98014425 @default.
• W156923741 hasPublicationYear "2008" @default.
• W156923741 type Work @default.
• W156923741 sameAs 156923741 @default.
• W156923741 citedByCount "1" @default.
• W156923741 crossrefType "journal-article" @default.
• W156923741 hasAuthorship W156923741A5013450626 @default.
• W156923741 hasConcept C115033672 @default.
• W156923741 hasConcept C127413603 @default.
• W156923741 hasConcept C150394285 @default.
• W156923741 hasConcept C161790260 @default.
• W156923741 hasConcept C178790620 @default.
• W156923741 hasConcept C185592680 @default.
• W156923741 hasConcept C194439259 @default.
• W156923741 hasConcept C2779647737 @default.
• W156923741 hasConcept C2780050857 @default.
• W156923741 hasConcept C2780564542 @default.
• W156923741 hasConcept C2780596425 @default.
• W156923741 hasConcept C42360764 @default.
• W156923741 hasConcept C518851703 @default.
• W156923741 hasConcept C518881349 @default.
• W156923741 hasConcept C548081761 @default.
• W156923741 hasConcept C68000547 @default.
• W156923741 hasConceptScore W156923741C115033672 @default.
• W156923741 hasConceptScore W156923741C127413603 @default.
• W156923741 hasConceptScore W156923741C150394285 @default.
• W156923741 hasConceptScore W156923741C161790260 @default.
• W156923741 hasConceptScore W156923741C178790620 @default.
• W156923741 hasConceptScore W156923741C185592680 @default.
• W156923741 hasConceptScore W156923741C194439259 @default.
• W156923741 hasConceptScore W156923741C2779647737 @default.
• W156923741 hasConceptScore W156923741C2780050857 @default.
• W156923741 hasConceptScore W156923741C2780564542 @default.
• W156923741 hasConceptScore W156923741C2780596425 @default.
• W156923741 hasConceptScore W156923741C42360764 @default.
• W156923741 hasConceptScore W156923741C518851703 @default.
• W156923741 hasConceptScore W156923741C518881349 @default.

• next