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- W1569280219 abstract "The meso- tetraarylporphyrin has been anchored to styrene- divinylbenzenecopolymers by reaction of meso- tetra (4-hydroxylphenyl ) porphyrin with chloromethylatedresin under mild condition. A number of polymer transition metal complexes have beenprepared with the polymer ligand and metal salts. The polymeric ligand and its complexeshave been characterized by electronic spectra, and vibrational spectra. Cyclohexene can behydrogenated with the polymeric porphyrin palladium complex(P-THPPPd) as catalyst,and its catalytic activity was influenced by the polarity of solvents, the contents of water inethanol or reaction temperature. However, its catalytic activity was lower for nitro groups,carbonyl groups and olefins with steric hindrance substituents, and showed no activity foraromatic rings under these conditions." @default.
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- W1569280219 date "1998-03-20" @default.
- W1569280219 modified "2023-09-28" @default.
- W1569280219 title "PREPARATION AND CATALYTIC BEHAVIOUR OF POLYMER-BOUND METALLOPORPHYRIN IN HYDROGENATION OF OLEFIN" @default.
- W1569280219 hasPublicationYear "1998" @default.
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