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- W1569295977 abstract "Dimethyl-and diphenylacetophosphides have been prepared by the reaction of ketene with the corresponding disubstituted phosphines. In the IR spectra two bands of νCO refer to the two conformations having different conjugation energies. In the UV spectra of these compounds the longwave absorption corresponding to the n → π* transition was discovered in which the atom of phosphorus participated. The mass and PMR spectra of acetophosphides have been investigated. The data obtained indicate the absence of amide-type resonance and the evidence of pπ-dπ conjugation in these compounds." @default.
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- W1569295977 date "1968-01-01" @default.
- W1569295977 modified "2023-09-30" @default.
- W1569295977 title "Hindered lone pair conjugation in the Vth group elements—I" @default.
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- W1569295977 doi "https://doi.org/10.1016/s0040-4020(01)98707-1" @default.
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