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- W1569330353 abstract "The interaction of α-chloromaleic anhydride (ClMAn) and allylcyclohexane (ACH) was studied. These monomers were found to make a charge-transfer (CT) complex at a 1 : 1 ratio. Copolymerization of ClMAn and ACH in solution gave a white powder in about 50% yield of which analytical data suggested that ClMAn and ACH are copolymerized in a 1 : 1 ratio. By heating the copolymer at 190°C for 1 h under reduced pressure, dehydrochlorination occurred quantitatively to generate a double bond in the polymer chain at the position of maleic anhydride moiety. The dehydrochlorinated copolymer was found to make a CT complex with acetone but the value of the formation constant was smaller than that of monomeric maleic anhydride." @default.
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- W1569330353 date "1993-01-01" @default.
- W1569330353 modified "2023-09-27" @default.
- W1569330353 title ".ALPHA.-Chloromaleic Anhydride-Allylcyclohexane Copolymer and Its Dehydrochlorination." @default.
- W1569330353 doi "https://doi.org/10.1248/cpb.41.2176" @default.
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