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• W1569379140 abstract "Despite the prolific use of (di-)NHC complexes in homogeneous catalysis, there are relatively few reports on their successful application in asymmetric transformations. In this work the atropisomeric binaphthyl backbone was combined with readily obtainable 1,2,3-triazolylidenes to develop a strongly electron-donating C2-symmetric ligand. The ligand was efficiently synthesized in a three-step procedure in an overall yield of 91 % starting from commercially available materials. Strategies for the synthesis of the corresponding di-NHC silver(I), palladium(II), rhodium(I), and iridium(I) complexes have been developed. The rhodium(I) complex was employed in the catalytic asymmetric hydrosilylation of ketones, providing good conversions at catalyst loadings as low as 0.2 mol-% and giving chiral inductions of up to 51 % ee." @default.
• W1569379140 created "2016-06-24" @default.
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• W1569379140 date "2015-05-27" @default.
• W1569379140 modified "2023-10-05" @default.
• W1569379140 title "Synthesis of BINAM‐Based Chiral Di‐1,2,3‐triazolylidene Complexes and Application of the Di‐NHC Rh ^I Catalyst in Enantioselective Hydrosilylation" @default.
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• W1569379140 doi "https://doi.org/10.1002/ejic.201500331" @default.
• W1569379140 hasPublicationYear "2015" @default.
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