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- W1569382404 abstract "Abstract Previous work on the induced isomerization of the carcinogenic arylhydroxamic acid, N-hydroxy-2-fluorenylacetamide, to the o-amidophenols, 1-hydroxy- and 3-hydroxy-2-fluorenylacetamide, by rat liver preparations has been extended. Examination of the substrate specificity of this enzymatic rearrangement suggests that the reaction is restricted to arylhydroxamic acids in which the nitrogen is linked to an aromatic system capable of extended conjugation. Determinations of the isotope content of 1-hydroxy- and 3-hydroxy-2-fluorenylacetamide isolated after incubation of the induced enzyme with N-hydroxy-2-fluorenylacetamide, labeled with 18O in the hydroxyl group, indicate that the hydroxyl group is transferred in toto from the nitrogen to the carbon atoms of the aromatic system located in a position ortho to the nitrogen. The data are compatible with an intramolecular rearrangement rather than with a previously suggested intermolecular mechanism involving addition of hydroxyl groups from the medium to the resonance forms of an amidonium ion." @default.
- W1569382404 created "2016-06-24" @default.
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- W1569382404 date "1972-02-01" @default.
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- W1569382404 title "The Conversion of the Carcinogen N-Hydroxy-2-fluorenylacetamide to o-Amidophenols by Rat Liver in Vitro" @default.
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- W1569382404 doi "https://doi.org/10.1016/s0021-9258(19)45659-7" @default.
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