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• W1569408117 abstract "Since the beginning of 199Os, the trend appears to have reverted to strong interactions between the fields of photosynthetic studies and bioinorganic chemistry largely because of the impact of molecular biology, particularly, site-specific mutagenesis and heterologous expression. This chapter summarizes these recent advances with emphasis on the part played by iron–sulfur centers in photosynthesis. If the inorganic chemistry of iron–sulfur centers has evolved tremendously since 1962, the modern notion of photosynthesis equally has little to do with its early versions. It is known that plant-type photosynthesis occurred first in eubacteria or more specifically in the ancestors of extant cyanobacteria, and was subsequently imported into eukaryotes via the events of endosymbiosis. As no photosynthetic mechanisms based on chlorophylls have so far been found in archaebacteria, the evolution of photosynthesis is considered to have exclusively occurred within the domain of eubacteria. In this domain, two further (anoxygenic) photosynthetic principles have been observed, each involving a cytochrome bc complex and only a single reaction center (RC) that resembles either photosystem I or photosystem II of oxygenic photosynthesis. The iron–sulfur centers participating in the light reactions of the three different photosynthetic principles are discussed in the chapter." @default.
• W1569408117 created "2016-06-24" @default.
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• W1569408117 date "1999-01-01" @default.
• W1569408117 modified "2023-10-18" @default.
• W1569408117 title "Iron-Sulfur Centers Involved in Photosynthetic Light Reactions" @default.
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