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• W1569409404 endingPage "247" @default.
• W1569409404 startingPage "147" @default.
• W1569409404 abstract "This chapter discusses the thermodynamic properties of the lanthanide (III) halides. The melting points in all four lanthanide trihalide series exhibit aminimum that shift from the heavy lanthanides to the light lanthanides as the atomic number of the halide increases. The variation in the heat capacity and entropy of the solid lanthanide trihalides can be described by a lattice contribution that linearly varies with the atomic number within each crystallographic class of compounds and an excess contribution that depends on the electronic configuration (crystal field) of the lanthanide ions. A distinct difference is observed between the heat capacity, and entropy of the hexagonal and monoclinic lanthanide trichlorides that clearly correlates with a distinct difference in molar volume between the two modifications. Both the effects are absent in the lanthanide trifluoride series. The properties of the liquid lanthanide trihalides depend strongly on the atomic number of the halide. The molecular parameters of the gaseous lanthanide trihalide molecules exhibit simple linear trends, with decreasing bond length and increasing vibrational frequencies, as the atomic number of the lanthanide ion increases." @default.
• W1569409404 created "2016-06-24" @default.
• W1569409404 creator A5052335305 @default.
• W1569409404 creator A5068209470 @default.
• W1569409404 date "2003-01-01" @default.
• W1569409404 modified "2023-09-30" @default.
• W1569409404 title "Thermodynamic properties of the lanthanide(III) halides" @default.
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