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• W1569446736 abstract "EMIRS spectra of the surface species resulting from methanol electrosorption on electrodispersed Pt were obtained by working under a wide range of experimental conditions, i.e. electrode roughness factor, methanol concentration and mean modulation potential. The intensity of the absorption band related to linearly adsorbed CO-species, COL, at ca. 2030–2080 cm−1 decreases on increasing the electrode roughness factor, a fact which is interpreted as a decrease in the CO adsorbate poisoning effect on electrodispersed Pt surfaces. As a consequence, under well-defined conditions, several bands are observed which might be assigned to adsorbed intermediates and reactive species. EMIRS also reveals a competition between COB and COL at high surface coverages. Spectral data for methanol electrooxidation on electrodispersed electrodes correlate well with the expected structure of this type of electrode." @default.
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• W1569446736 date "1991-02-01" @default.
• W1569446736 modified "2023-10-16" @default.
• W1569446736 title "Electromodulated infrared spectroscopy of methanol electrooxidation on electrodispersed platinum electrodes" @default.
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• W1569446736 doi "https://doi.org/10.1016/0022-0728(91)85464-z" @default.
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