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- W1569506988 abstract "A comprehensive and detailed physicochemical model is presented for sample retention in liquid-solid chromatography, using either classical adsorbents such as silica or alumina, or polar-bonded-phase packings such as aminoalkyl, diol, etc. Application of the model to a large mass of data for wide variation of adsorbent, mobile phase and solute shows good agreement between theory and experiment. The model is based upon displacement and localization phenomena as primary contributions to retention. Localization phenomena can be sub-classified into at least four distinct effects, and these latter effects can be correlated with the geometry of adsorption sites in various adsorbents. A preliminary model of solute—solvent hydrogen bonding in these liquid—solid chromatographic systems is presented and compared with limited experimental data. The latter effect can be significant in these systems." @default.
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- W1569506988 date "1983-01-01" @default.
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- W1569506988 title "Mobile phase effects in liquid-solid chromatography" @default.
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- W1569506988 doi "https://doi.org/10.1016/s0021-9673(01)88270-4" @default.
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