FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1569512989> ?p ?o ?g. }

• W1569512989 endingPage "43" @default.
• W1569512989 startingPage "29" @default.
• W1569512989 abstract "The aim of this work is to verify by preparative organo-electrosynthesis the theoretical analyses of consecutive reactions which follow the anodic generation of radicals in the presence of olefinic scavengers as given in Part I [1]. The addition of anodically generated azide radicals to styrene if performed in acetonitrile and using Pt-anodes is a relatively unselective reaction. Besides the undesired annihilation of azide radicals which yields N6 (with eventual formation of N2) there are found in the product mixture at least nine different organic compounds containing the azido group. Main products are 1,2-diazido-phenyl-ethane and 1,4-diazido-2,3-diphenyl-butane which are produced with current efficiencies between 8 and 90%. Side products being generated with efficiencies between 0 and 10% are 1-azido-2-phenyl-ethane, 1-azido-2-phenyl-ethylene, 1-azido-2-hydroxy-2-phenyl-ethane, 1-methyl-2-(2-azido-1-phenyl-ethyl)-2,3,4,5,-N-tetrazole, as “monomeric” products and three “dimeric” compounds: 1,4-diazido-1,3-diphenyl-butane, 4-azido-1,3-diphenyl-butene-1 and its isomer 1-azido-2,4-diphenyl-butene-1. Most of these products, and especially the two main products, are generated by typical homogeneous radical-reaction sequences which are initiated by the addition of anodically produced azide radicals, to styrene within a reaction layer of some 10 nm thickness. Detailed investigation of the influence of reaction parameters and additive effects on yields makes it clear that all consecutive reactions are homogeneous reactions and that the first addition radical may not be further oxidized. Predictions concerning the selectivity of this type of organo-synthetic reaction based on a theoretical treatment of the electrode and homogeneous reactions [1] and on numerical rate data obtained from electrode kinetic measurements [2] have been verified to an extent which permits a generalization of the given results for product optimization of other comparable electrolysis processes. A redetermination of the rate constant for addition of N3-radicals to styrene from the preparative data gives very good agreement with rate determined from electrode kinetic measurements." @default.
• W1569512989 created "2016-06-24" @default.
• W1569512989 creator A5007757524 @default.
• W1569512989 creator A5046783643 @default.
• W1569512989 date "1983-09-01" @default.
• W1569512989 modified "2023-09-27" @default.
• W1569512989 title "Addition reactions of anodically generated radicals to olefins" @default.
• W1569512989 cites W1602692089 @default.
• W1569512989 cites W1965864683 @default.
• W1569512989 cites W1968931610 @default.
• W1569512989 cites W1992429291 @default.
• W1569512989 cites W1993154435 @default.
• W1569512989 cites W2001776166 @default.
• W1569512989 cites W2002709581 @default.
• W1569512989 cites W2002929142 @default.
• W1569512989 cites W2006970345 @default.
• W1569512989 cites W2008717297 @default.
• W1569512989 cites W2012310581 @default.
• W1569512989 cites W2012687124 @default.
• W1569512989 cites W2019401305 @default.
• W1569512989 cites W2026107573 @default.
• W1569512989 cites W2029782443 @default.
• W1569512989 cites W2033253695 @default.
• W1569512989 cites W2038578933 @default.
• W1569512989 cites W2050217899 @default.
• W1569512989 cites W2054342805 @default.
• W1569512989 cites W2066886356 @default.
• W1569512989 cites W2161063169 @default.
• W1569512989 cites W2164081155 @default.
• W1569512989 cites W2909521257 @default.
• W1569512989 cites W2951091877 @default.
• W1569512989 doi "https://doi.org/10.1016/s0022-0728(83)80529-4" @default.
• W1569512989 hasPublicationYear "1983" @default.
• W1569512989 type Work @default.
• W1569512989 sameAs 1569512989 @default.
• W1569512989 citedByCount "10" @default.
• W1569512989 countsByYear W15695129892014 @default.
• W1569512989 crossrefType "journal-article" @default.
• W1569512989 hasAuthorship W1569512989A5007757524 @default.
• W1569512989 hasAuthorship W1569512989A5046783643 @default.
• W1569512989 hasConcept C139066938 @default.
• W1569512989 hasConcept C15920480 @default.
• W1569512989 hasConcept C161790260 @default.
• W1569512989 hasConcept C166940927 @default.
• W1569512989 hasConcept C178790620 @default.
• W1569512989 hasConcept C185592680 @default.
• W1569512989 hasConcept C188027245 @default.
• W1569512989 hasConcept C18950567 @default.
• W1569512989 hasConcept C2777566558 @default.
• W1569512989 hasConcept C2778717364 @default.
• W1569512989 hasConcept C2780827033 @default.
• W1569512989 hasConcept C2780997848 @default.
• W1569512989 hasConcept C521977710 @default.
• W1569512989 hasConcept C75473681 @default.
• W1569512989 hasConceptScore W1569512989C139066938 @default.
• W1569512989 hasConceptScore W1569512989C15920480 @default.
• W1569512989 hasConceptScore W1569512989C161790260 @default.
• W1569512989 hasConceptScore W1569512989C166940927 @default.
• W1569512989 hasConceptScore W1569512989C178790620 @default.
• W1569512989 hasConceptScore W1569512989C185592680 @default.
• W1569512989 hasConceptScore W1569512989C188027245 @default.
• W1569512989 hasConceptScore W1569512989C18950567 @default.
• W1569512989 hasConceptScore W1569512989C2777566558 @default.
• W1569512989 hasConceptScore W1569512989C2778717364 @default.
• W1569512989 hasConceptScore W1569512989C2780827033 @default.
• W1569512989 hasConceptScore W1569512989C2780997848 @default.
• W1569512989 hasConceptScore W1569512989C521977710 @default.
• W1569512989 hasConceptScore W1569512989C75473681 @default.
• W1569512989 hasIssue "1-2" @default.
• W1569512989 hasLocation W15695129891 @default.
• W1569512989 hasOpenAccess W1569512989 @default.
• W1569512989 hasPrimaryLocation W15695129891 @default.
• W1569512989 hasRelatedWork W1569512989 @default.
• W1569512989 hasRelatedWork W1954835032 @default.
• W1569512989 hasRelatedWork W1970196854 @default.
• W1569512989 hasRelatedWork W1995288998 @default.
• W1569512989 hasRelatedWork W2024452683 @default.
• W1569512989 hasRelatedWork W2057193264 @default.
• W1569512989 hasRelatedWork W2108456125 @default.
• W1569512989 hasRelatedWork W2587175364 @default.
• W1569512989 hasRelatedWork W2952655335 @default.
• W1569512989 hasRelatedWork W4286785788 @default.
• W1569512989 hasVolume "154" @default.
• W1569512989 isParatext "false" @default.
• W1569512989 isRetracted "false" @default.
• W1569512989 magId "1569512989" @default.
• W1569512989 workType "article" @default.