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- W1569543332 abstract "The electronic absorption spectra of mono-hydrogenated carbon chain anions C2nH− (n=5–10) have been measured in the gas-phase and in 6 K neon matrices (n=8–12). The techniques of resonant two-color electron photodetachment in the gas-phase and absorption spectroscopy of mass-selected anions in neon matrix were used. A homologous series is observed, with band system origins shifting from 304 nm for C10H− to 590 nm for C20H−. In conjunction with ab initio calculations the band systems are attributed to a Σ+1←X 1Σ+ transition of linear acetylenic anions. Another near lying electronic transition due to a second isomer is also apparent for C10H− up to C24H−. Comparison with tables of the known diffuse interstellar bands indicates possible matches for the origin bands of the C18H− and C20H− isomers." @default.
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- W1569543332 date "1999-11-22" @default.
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- W1569543332 title "Electronic spectra of carbon chain anions: C2nH− (n=5–12)" @default.
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- W1569543332 doi "https://doi.org/10.1063/1.479842" @default.
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