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- W1569569013 abstract "Furopelargones A and B are shown to have structures III and IV, respectively. Ozonolysis of furopelargone A led to the optical antipode VIIa of trans-cis-nepetonic acid, the structure and stereochemistry of which was ascertained by degradation to (−)-trans-cis-nepetic acid (XIIa) and to (+)-3-methylcyclopentanone (XVIIIc). Only four structures (XIX to XXII) were then possible for furopelargone A. Hydrogenation of the natural product afforded a ketol, the mass spectrum of which was found to be compatible only with XXIII, arising from XIX. Furopelargone B was shown to be an epimer of furopelargone A in the position α to the carbonyl group." @default.
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- W1569569013 date "1964-01-01" @default.
- W1569569013 modified "2023-10-14" @default.
- W1569569013 title "The constitution of two new sesquiterpenic ketones" @default.
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- W1569569013 doi "https://doi.org/10.1016/s0040-4020(01)99180-x" @default.
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