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- W1569592409 abstract "Biomimetic microporous structures were prepared by in situ laboratory zeolitization of a silica-rich plant, member of the Equisetophyta family. Leaves and stems of the dry plant were subjected to hydrothermal treatment into a clear ZSM-5 precursor solution. Highly reactive biomorphic silica deposited at the epidermal surface of the plant successfully promoted zeolite growth and provided composites containing up to 70 wt. % ZSM-5. The zeolite/plant composites were transformed into all-zeolite materials by high temperature calcination. Both the as-synthesized zeolite/plant composites and all-zeolite replicas were studied by XRD, TG/DTA analysis, SEM, TEM, N2 adsorption measurements. The analysis of the synthesized composites and their replicas showed that tiny zeolite nanoparticles crystallizing at the tissues of the biotemplate generated mesopores. Thus, the utilization of a biological template allowed to synthesize a micro-/mesoporous material with specific macromorphological features." @default.
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- W1569592409 date "2004-01-01" @default.
- W1569592409 modified "2023-10-18" @default.
- W1569592409 title "Dual templating function of Equisetum arvense in the preparation of zeolite macrostructures" @default.
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- W1569592409 doi "https://doi.org/10.1016/s0167-2991(04)80855-3" @default.
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