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- W1569596823 abstract "Abstract The prismane cluster [Cu4Mo2S6][(C6H5)3P]2(C6H7N)2O2·2C6H7N has been prepared by the reaction of [NH4]2MoO2S2 with CuBr and PPh3 in 2-picoline. Its molecular structure was determined by single-crystal X-ray analysis. The compound crystallizes in the monoclinic space group P21/n with a = 12.149(2), b = 17.152(2), c = 15.793(2)A, β = 105.40(2)°, and Z=2. The X-ray structure (R; Rw = 0.046; 0.048) revealed a 12-atom Cu4Mo2S6 prismane which can be envisaged as consisting of two MoOS3 units connected on adjacent edges by two different groups, [C6H7NCu] and [(C6H5)3PCu]." @default.
- W1569596823 created "2016-06-24" @default.
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- W1569596823 date "1998-11-01" @default.
- W1569596823 modified "2023-10-01" @default.
- W1569596823 title "A NOVEL PRISMANE CLUSTER. SYNTHESIS AND CRYSTAL STRUCTURE OF A DIMER OF [(TRIPHENYLPHOSPHINE) COPPER(2-PICOLINE)COPPER] OXOTRITHIOMOLYBDENUM, [Cu4Mo2S6][(C6H5)3P]2(C6H7N)2O2·2C6H7N" @default.
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- W1569596823 doi "https://doi.org/10.1080/00958979808047193" @default.
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