Matches in SemOpenAlex for { <https://semopenalex.org/work/W1569646532> ?p ?o ?g. }
- W1569646532 endingPage "239" @default.
- W1569646532 startingPage "109" @default.
- W1569646532 abstract "Abstract Polynuclear complexes of rare-earth elements characterized by their well-defined, cluster-like core structures are a class of interesting compounds with pleasing molecular structures and potential useful applications. Their synthetic and structural chemistry has been developed rapidly in the last two decades, and a review of this subject is therefore timely. Presented in this chapter are the large number of cluster compounds of rare-earth elements appeared in the literature up to 2008. The discussion of this vast number of cluster species is organized according to the distinct synthetic methods by which they are produced, that is, those obtained under conditions typical of organometallic synthesis and those by deliberate hydrolysis of mononuclear or lower-nuclearity precursors. The common driving force behind the assembly of these cluster species is the inherent tendency of the bulky metal atoms to satisfy their coordination number requirements. The clustering of the individual metal atoms is facilitated by the use of multidentate chelating and bridging ligands, mostly oxygen-based due to the oxophilicity of these unique metal elements. Other heteroatoms, including N, chalcogens, halogens, and H are also frequently found in the coordination sphere, generally in the form of small-unit ligands. With the unabated enthusiasm and efforts from researchers over the world, this cluster chemistry of rare-earth elements has now been developed into a unique research area, and a number of important applications (chemical, biomedical, and materials) have either been realized or envisioned. It is reasonable to predict that activities in this particular direction of chemical research will continue to grow with a high possibility of finding many new species with pleasing structures and useful applications." @default.
- W1569646532 created "2016-06-24" @default.
- W1569646532 creator A5018664048 @default.
- W1569646532 date "2010-01-01" @default.
- W1569646532 modified "2023-09-27" @default.
- W1569646532 title "Chapter 245 Cluster Compounds of Rare-Earth Elements" @default.
- W1569646532 cites W11455398 @default.
- W1569646532 cites W1560570736 @default.
- W1569646532 cites W169523316 @default.
- W1569646532 cites W1752316340 @default.
- W1569646532 cites W1963513960 @default.
- W1569646532 cites W1963749305 @default.
- W1569646532 cites W1963956125 @default.
- W1569646532 cites W1964889014 @default.
- W1569646532 cites W1965100861 @default.
- W1569646532 cites W1966063987 @default.
- W1569646532 cites W1968017051 @default.
- W1569646532 cites W1971872623 @default.
- W1569646532 cites W1972097509 @default.
- W1569646532 cites W1974935857 @default.
- W1569646532 cites W1975468004 @default.
- W1569646532 cites W1976472960 @default.
- W1569646532 cites W1976628641 @default.
- W1569646532 cites W1978471370 @default.
- W1569646532 cites W1978769998 @default.
- W1569646532 cites W1979737248 @default.
- W1569646532 cites W1980065864 @default.
- W1569646532 cites W1981898910 @default.
- W1569646532 cites W1982154063 @default.
- W1569646532 cites W1982640972 @default.
- W1569646532 cites W1984044268 @default.
- W1569646532 cites W1984112066 @default.
- W1569646532 cites W1984437872 @default.
- W1569646532 cites W1985745429 @default.
- W1569646532 cites W1986583508 @default.
- W1569646532 cites W1986979698 @default.
- W1569646532 cites W1987829211 @default.
- W1569646532 cites W1989099386 @default.
- W1569646532 cites W1990250276 @default.
- W1569646532 cites W1990252002 @default.
- W1569646532 cites W1993682216 @default.
- W1569646532 cites W1994360678 @default.
- W1569646532 cites W1995048699 @default.
- W1569646532 cites W1997646820 @default.
- W1569646532 cites W1997652393 @default.
- W1569646532 cites W1998349906 @default.
- W1569646532 cites W1998950262 @default.
- W1569646532 cites W2004925437 @default.
- W1569646532 cites W2005357799 @default.
- W1569646532 cites W2006947665 @default.
- W1569646532 cites W2008071581 @default.
- W1569646532 cites W2008484960 @default.
- W1569646532 cites W2010126880 @default.
- W1569646532 cites W2013299343 @default.
- W1569646532 cites W2014855681 @default.
- W1569646532 cites W2016623561 @default.
- W1569646532 cites W2022176300 @default.
- W1569646532 cites W2023083117 @default.
- W1569646532 cites W2023400106 @default.
- W1569646532 cites W2023985763 @default.
- W1569646532 cites W2024120411 @default.
- W1569646532 cites W2025056855 @default.
- W1569646532 cites W2025107705 @default.
- W1569646532 cites W2026037981 @default.
- W1569646532 cites W2026288971 @default.
- W1569646532 cites W2027435994 @default.
- W1569646532 cites W2027562297 @default.
- W1569646532 cites W2027686003 @default.
- W1569646532 cites W2028904006 @default.
- W1569646532 cites W2028984960 @default.
- W1569646532 cites W2031980562 @default.
- W1569646532 cites W2034017956 @default.
- W1569646532 cites W2034117337 @default.
- W1569646532 cites W2035361319 @default.
- W1569646532 cites W2036344206 @default.
- W1569646532 cites W2036513611 @default.
- W1569646532 cites W2036608134 @default.
- W1569646532 cites W2037879463 @default.
- W1569646532 cites W2038064532 @default.
- W1569646532 cites W2039789849 @default.
- W1569646532 cites W2043480272 @default.
- W1569646532 cites W2045031649 @default.
- W1569646532 cites W2046266901 @default.
- W1569646532 cites W2047998676 @default.
- W1569646532 cites W2048034907 @default.
- W1569646532 cites W2048782544 @default.
- W1569646532 cites W2049440437 @default.
- W1569646532 cites W2051263337 @default.
- W1569646532 cites W2052413837 @default.
- W1569646532 cites W2052623132 @default.
- W1569646532 cites W2053051631 @default.
- W1569646532 cites W2053874902 @default.
- W1569646532 cites W2054005476 @default.
- W1569646532 cites W2055279757 @default.
- W1569646532 cites W2056188057 @default.
- W1569646532 cites W2057397220 @default.
- W1569646532 cites W2059008011 @default.
- W1569646532 cites W2060687927 @default.