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- W1569652166 abstract "A chiral α-sulfinyl α, β-unsaturated ketone served as a good chiral diene or enophile in intramolecular Lewis acid-catalyzed asymmetric pericyclic reactions, giving hetero-Diels-Alder reaction products, together with ene reaction products in some cases, in high optical yields. The reaction pathways for Diels-Alder or ene reactions were readily controlled depending on the Lewis acids used. A chiral α-sulfinyl α, β-unsaturated ester served as a good enophile to give ene reaction products with high enantioselectivity. The mechanistic pathway for the asymmetric induction is proposed on the basis of the stereochemical results obtained." @default.
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- W1569652166 date "1993-01-01" @default.
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- W1569652166 title "Studies on Chiral Organosulfur Compounds. III. Lewis Acid-Catalyzed Intramolecular Asymmetric Pericyclic Reactions of Chiral .ALPHA.-Acetyl and Methoxycarbonylvinylic Sulfoxides." @default.
- W1569652166 doi "https://doi.org/10.1248/cpb.41.666" @default.
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