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- W1569696749 abstract "The behaviour of a copper(II)-selective electrode made of ternary copper/silver sulfide, in the presence of complexing agents is discussed. Potential vs. pH curves indicate that in the case of Trien and Tetren, the electrode response reflects the situation in the bulk solution when both the free ligand and its copper(II) complex are present; when only the ligand is present, a small amount of the complex is probably formed near the surface, by dissolution of the membrane material. Similar results were found with citrate and glycine. In the case of EDTA and NTA, however, the response of the electrode is quite different; the concentrations of free copper(II) measured are higher than those expected from chemical equilibrium calculations for the bulk solution. The curves for solutions with and without the complex coincide and show an anomalous dependence on the sidereaction coefficient, αL(H). No explanation has been found for this behaviour. There is good agreement between stability constants for copper complexes or precipitates of Trien, Tetren, hydroxide and sulfide, obtained with this electrode and those given in the literature. The results indicate that Tetren or Trien should be preferred to EDTA and NTA for the preparation of metal buffer solutions." @default.
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- W1569696749 date "1978-01-01" @default.
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- W1569696749 title "The formation of mixed copper sulfide—silver sulfide membranes for copper(II)-selective electrodes" @default.
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- W1569696749 doi "https://doi.org/10.1016/s0003-2670(01)93390-2" @default.
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