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- W1569710692 abstract "Treatment of bis(cyanamide) [M(N≡CNEt2)2L4](BPh4)2 and bis(cyanoguanidine) [M{N≡CN(H)C(NH2)=NH}2L4](BPh4)2 complexes [M = Fe, Ru, Os; L = P(OEt)3] with an excess of amine RNH2 (R = nPr, iPr) affords mixed-ligand complexes with cyanamide and amine [M(NH2R)(N≡CNEt2)L4](BPh4)2 (1a–5a) and [M(NH2R){N≡CN(H)C(NH2)=NH}L4](BPh4)2 (1b, 2b). The complexes were characterized by spectroscopy and X-ray crystal structure determination of [M(NH2iPr)(N≡CNEt2){P(OEt)3}4](BPh4)2 [M = Ru (3a), Os (5a)]." @default.
- W1569710692 created "2016-06-24" @default.
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- W1569710692 date "2015-02-06" @default.
- W1569710692 modified "2023-09-22" @default.
- W1569710692 title "Reactivity with Amines of Bis(cyanamide) and Bis(cyanoguanidine) Complexes of the Iron Triad" @default.
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- W1569710692 doi "https://doi.org/10.1002/zaac.201400591" @default.
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