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- W1569754267 abstract "Abstract Access to α‐glycosyl azides in modest to high diastereoselectivity by way of TMSN 3 ring‐opening of 1,6‐anhydro sugars mediated by TMSOTf is reported. The reaction tolerates a wide variety of functional groups including alcohol, alkyne, azide and ester groups. The efficient synthesis of a pseudopentasaccharide in five steps from commercially available levoglucosan by way of a “click‐click” approach is presented to highlight the interest of the TMSN 3 ring‐opening reaction." @default.
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- W1569754267 date "2013-02-18" @default.
- W1569754267 modified "2023-10-18" @default.
- W1569754267 title "Stereoselective Synthesis of α-Glycosyl Azides by TMSOTf-Mediated Ring Opening of 1,6-Anhydro Sugars" @default.
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- W1569754267 doi "https://doi.org/10.1002/ejoc.201201580" @default.
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