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- W1569762157 abstract "Publisher Summary This chapter reviews that the account of an infant discipline of metallacalixarenes, the metallo-version of heterocalixarenes and a unique category of organo-inorganic hybrid systems elaborates many of their distinctive features with respect to other synthetic receptors. Their metallic components are primarily responsible for the multifold positive charge of the species that visibly constitute attractive hosts for anions so significant in biological reactions. The intrinsic magneto-electrical and structural contribution of metals could impart in metallacalixarenes such unusual features in target functional materials. An abundant use of nucleobases in their designs and large non-existent in parent heterocalixarenes, points to their relevance in mimicking supramolecular phenomenon in biological systems. Only four model heterocycles have so far been used in evolving metallacalixarenes, points to the lack of awareness amongst practitioners of heterocyclic chemistry. It is hoped that their involvement in the exploration of this interfacial area will prove increasingly fruitful." @default.
- W1569762157 created "2016-06-24" @default.
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- W1569762157 date "2008-01-01" @default.
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- W1569762157 title "Chapter 3 Metallacalixarenes: Organo-Inorganic Hybrid Molecular Architectures" @default.
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- W1569762157 doi "https://doi.org/10.1016/s0065-2725(07)00003-7" @default.
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