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- W1569762455 abstract "Abstract The 13C NMR of squalene in tetrahydrofuran-d8 is sufficiently resolved for T1 measurements (by the inversion-recovery method) to permit the derivation of relative mobilities along the chain On addition of water, no detectable changes occur to the point of saturation, consistent with the absence of conformational changes (coiling) with change in solvent polarity. On the basis of silver-ion induced carbon chemical shifts, complexation occurs unselectively at all three double bonds in THF, but with some preference for the terminal double-bond in part-aqueous solutions. Squalane shows similar mobility to the unsaturated compound but complications from line overlap are apparent. In squalene-2,3-glycol, the polar end of the molecule is of lower mobility, and this difference is accentuated on addition of water consistent with specific association of water at the OH terminus." @default.
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- W1569762455 date "1977-01-01" @default.
- W1569762455 modified "2023-09-23" @default.
- W1569762455 title "An assessment of the mobility of squalene in part-aqueous solutions from carbon magnetic resonance spin-lattice relaxation times" @default.
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- W1569762455 doi "https://doi.org/10.1016/0040-4020(77)80204-4" @default.
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