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- W1569785021 abstract "Heats of mixing (ΔHm) for three polymers in three solvents have been measured using a TIAN-CALVET microcalorimeter. ΔHm are positive (endothermic) and are shown to be in good quantitative agreement with HILDEBRAND-SCATCHARD expectations. These results offer the occation to consider a new contribution to ΔHm which has ben ignored in currently accepted thermodynamic theories and which could explain the large deviations from the HILDEBRAND treatment of ΔHm, occurring for polymer/non Θ-solvent systems. Für drei Polymere wurden in drei Lösungsmitteln die Mischungswärmen (ΔHM) mit einem TIAN-CALVET-Mikrokalorimeter gemessen. Die ΔHm-Werte sind positiv (endotherme Systeme) und lassen sich quantitativ durch die HILDEBERAND-SCATCHARD-Beziehung erfassen. Das andersartige Verhalten von Polymeren in Nicht-Θ-Lösungsmitteln kann durch einen Beitrag zu ΔHm erklärt werden, der bei den bisherigen thermodynamischen Theorien unberücksichtigt blieb." @default.
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- W1569785021 date "1966-03-18" @default.
- W1569785021 modified "2023-10-16" @default.
- W1569785021 doi "https://doi.org/10.1002/macp.1966.020920108" @default.
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