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- W1569794501 abstract "The stochastic graph theory has been applied to define axiomatically intermolecular and intramolecular reactions, as well as the phenomenon of gelation, equations for determining the date of appearance of the phenomenon, and its domain for three topologically possible principle types of systems have been given. The experimental values for gel points in structurally different systems, being in good agreement with the theoretical (±1 to 2%), lead us to conclude that the observed slight differences near the limiting conditions of the domain are certainly due to a non-equiprobable behavior of steric origin. Assimilating crosslinking (and also vulcanization) to a process of gelation taking place in two distinct and successive phases seems to lead to results in conformity with the idea of evolution and with the values of characteristic magnitudes of these techniques in as much as their experimental conditions are not much different from those theoretical herein admitted." @default.
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- W1569794501 date "1967-01-01" @default.
- W1569794501 modified "2023-09-23" @default.
- W1569794501 title "La Réticulation: Un Aspect Particulièr de la Gélification Selon la Theorie des Graphes Stochastiques" @default.
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- W1569794501 doi "https://doi.org/10.1002/polc.5070160751" @default.
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