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- W1569797739 abstract "Abstract The binuclear complexes [Mo(CO) 3 L 2 ] 2 (L &2.dbnd; maleic acid or fumaric acid esters) react with the N-heterocyclics 2,2'-bipyridine (Bipy) or 1,10-phenanthroline (Phen) under elimination of CO giving the mononuclear dicarbonyl compounds Mo(CO) 2 QL 2 (Q &2.dbnd; Bipy, Phen) with cis 3-carbonyl ligands: [Mo(CO) 3 L 2 ] 2 + 2 Q - 2 Mo(CO) 2 QL 2 + 2 CO In the reaction of Phen together with fumaric acid esters with C 7 H 8 Mo(CO) 3 , tricarbonyl complexes with a meridional arrangement of the CO ligands are formed: C 7 H 8 Mo(CO) 3 + Phen + L → mer -Mo(CO) 3 PhenL + C 7 -H 8 In the case of the dibutyl fumarate derivative (L &2.dbnd; DBFU), isomerization to the facial CO arrangement is effected by a small excess of the ester: In solution the mer-Mo(CO) 3 PhenL complexes slowly undergo carbonyl disproportionation: Possible mechanisms for these reactions are discussed." @default.
- W1569797739 created "2016-06-24" @default.
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- W1569797739 date "1976-07-01" @default.
- W1569797739 modified "2023-09-27" @default.
- W1569797739 title "Maleinsäure- und fumarsäureester als liganden in metallcarbonyl-komplexen" @default.
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- W1569797739 doi "https://doi.org/10.1016/s0022-328x(00)96148-5" @default.
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