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- W1569884485 abstract "Abstract The reactions of BX 3 (X = Cl, Br) with 7‐R‐7‐phosphanorbornadiene–M(CO) 5 (M = Mo, W) complexes ( 1 ) yields products 2 and 4 in which the RP–M(CO) 5 unit is inserted into one of the carboxyl units of the phthalic derivative as a result of the collapse of the bridge. When X = Br, 4 cyclizes to give new six‐membered heterocycles 5 with quasiplanar structures. When treated by an excess of BBr 3 , heterocycles 5 undergo ring contraction to afford five‐membered oxocyclic products 6 ." @default.
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- W1569884485 date "2014-11-25" @default.
- W1569884485 modified "2023-10-17" @default.
- W1569884485 title "The Unexpected Reactions of Boron Trihalides with 7‐Phosphanorbornadiene Complexes" @default.
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- W1569884485 doi "https://doi.org/10.1002/ejic.201402847" @default.
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