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• W1569884694 abstract "A new optically active tetraazamacrocycle ligand, 2/? 37?-cyclohexano-1,4,7,10-tetraazacyclododecane was covalently anchored on the surface of micelle-templated silicate (MTS) by a coupling reaction on previously grafted 3-chloropropyl chains. After alkylation of the residual secondary amine groups of the grafted ligands with propylene oxide, these were metallated with manganese (II) salts. During the various modifications, the textural characteristics of the support were preserved. Using iodosylbenzene as oxygen donor, this material successfully catalyzed heterogeneous epoxidation of trans-β-methylstyrene into 1R,2R-trans-1-phenylpropylene oxide with a very high enantioselectivity (ee. 76%)." @default.
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• W1569884694 date "2000-01-01" @default.
• W1569884694 modified "2023-09-25" @default.
• W1569884694 title "New Chiral Hybrid Organic-Inorganic Mesoporous Materials for Enantioselective Epoxidation." @default.
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• W1569884694 doi "https://doi.org/10.1016/s0167-2991(00)80282-7" @default.
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