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- W1569892577 abstract "Dimethylamine is added to the triple bond of phenylacetylenyl(ethoxy)carbenepentacarbonyl-chromium and -tungsten at −20°C in diethylether while at −115°C, −80°C, respectively, selective aminolysis of the carbene-alkoxy group takes place. This way of reaction is referred to well known kinetic data of the aminolysis of alkoxy carbene complexes and the electronic properties of dialkylamino groups. Phenylacetylenyl(äthoxy)carben-pentacarbonyl-chrom und -wolfram addieren bei −20°C in Diäthyläther Dimethylamin an die Dreifachbindung, während bei −115°C bzw. −80°C selektiv Aminolyse der Carben-Alkoxy-Gruppe erfolgt. Das Reaktionsverhalten wird auf gut bekannte kinetische Daten für die Aminolyse von Alkoxy-carbenkomplexen und die elektronischen Eigenschaften von Dialkylaminogruppen zurückgeführt." @default.
- W1569892577 created "2016-06-24" @default.
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- W1569892577 date "1977-05-01" @default.
- W1569892577 modified "2023-09-26" @default.
- W1569892577 title "Übergangsmetall—carben-komplexe" @default.
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- W1569892577 doi "https://doi.org/10.1016/s0022-328x(00)91358-5" @default.
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