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- W1570208453 abstract "The effects of the type and content of comonomers on the rheological properties of acrylic copolymers in 1-butyl-3-methylimidazolium chloride ([BMIM]Cl) were explored. According to the de Gennes scaling law for solution, comparison of intrinsic viscosity and scaling analysis of the exponent in the specific viscosity- and relaxation time-concentration power law indicated that solution of both polyacrylonitrile (PAN) homo-polymer and copolymer poly(acrylonitrile-co-methyl acrylate) (poly(AN-co-MA)) in [BMIM]Cl behave in the same manner as neutral polymer in a θ-solvent. However, [BMIM]Cl acts as a more good solvent for poly(acrylonitrile-co-acrylamide) (poly(AN-co-AM)). The dissolution and unique rheological behavior of such solutions have been attributed to the interactions between copolymer chains and [BMIM]Cl. The interactions between nitrile group (−C≡N) and 1-butyl-3-methylimidazolium cation ([BMIM]+) should interrupt and break the dipolar-dipolar interactions of PAN resulting in the subsequent dissolution of the polymer in [BMIM]Cl. Such interactions between −C≡N and [BMIM]+ ion are still dominated by the solvating ability of poly(AN-co-MA) in [BMIM]Cl, even though carbonyl group (C=O) in MA repeating unit could coordinate to cation of the ionic liquid. The salvation capacity of [BMIM]Cl for poly(AN-co-AM) can be evidently improved due to the extra hydrogen bond interactions between −NH2 group of AM and anion of [BMIM]Cl. Copyright © 2012 John Wiley & Sons, Ltd." @default.
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- W1570208453 date "2012-07-03" @default.
- W1570208453 modified "2023-10-16" @default.
- W1570208453 title "Understanding the interactions in acrylic copolymer/1-butyl-3-methylimidazolium chloride from solution rheology" @default.
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- W1570208453 doi "https://doi.org/10.1002/pat.3055" @default.
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