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- W1570210093 abstract "The thermal behavior and kinetic parameters of the decomposition reaction of triethylene glycol dinitrate (TEGDN) in a temperature-programmed mode at different pressures (0.1, 2, 4 and 6 MPa) have been investigatedby means of DSC and TG-DTG. The results show that the properties of the thermal decomposition of TEGDN are affected by the change of pressure, and the kinetic model function, the apparent activation energy Ea and pre-exponential factor A of this reaction are 2(1-α)[-ln(1-α)]1/2, 106.54 kJ·mol^-1 and 109^9.17 at 0.1 MPa,and 120.82 kJ·mol^-1 and 10^10.56 S^-1 at 2 MPa, respectively. The critical temperature of thermal explosion of TEGDN obtained by the values Teo and Tpo of the onset temperature Te and the peak temperature Tp when the heat-ing rate tends to zero are 191.05, 209.86℃ at 0.1 MPa, 207.59 and 221.65 ℃ at 2 MPa, respectively." @default.
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- W1570210093 date "2004-01-01" @default.
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- W1570210093 title "Thermal Decomposition Kinetics of Triethylene Glycol Dinitrate" @default.
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