Matches in SemOpenAlex for { <https://semopenalex.org/work/W1570255344> ?p ?o ?g. }
Showing items 1 to 77 of
77
with 100 items per page.
- W1570255344 endingPage "2751" @default.
- W1570255344 startingPage "2742" @default.
- W1570255344 abstract "A computer model which simulates the operation of a flow‐through Raney nickel powder electrocatalytic hydrogenation reactor for the synthesis of sorbitol from glucose with simultaneous evolution has been developed. The model utilizes porous electrode theory, considers both mass‐transfer and surface kinetics effects, and contains no adjustable parameters. Hydrogen evolution on Raney nickel is described by a Volmer‐Heyrovský rate expression. The rate equation for glucose hydrogenation is identical to that for the chemical catalytic synthesis of sorbitol with pressurized gas. For constant‐current reactor operation, computed sorbitol current efficiencies match well with experimental data for a range of current densities (0.0053 to 0.021 A/cm2) and glucose feed concentrations (0.4 to 1.6M), with an average error of 8.8%. Calculations show that a large fraction of adsorbed hydrogen on the nickel cathode surface is produced by the oxidation of electrogenerated via the backward Heyrovský reaction. According to the model, significantly higher sorbitol current efficiencies can be achieved by pulsing the current to the reactor." @default.
- W1570255344 created "2016-06-24" @default.
- W1570255344 creator A5057198789 @default.
- W1570255344 creator A5076390789 @default.
- W1570255344 date "1994-10-01" @default.
- W1570255344 modified "2023-10-02" @default.
- W1570255344 title "The Electrocatalytic Hydrogenation of Glucose: II . Raney Nickel Powder Flow‐Through Reactor Model" @default.
- W1570255344 doi "https://doi.org/10.1149/1.2059198" @default.
- W1570255344 hasPublicationYear "1994" @default.
- W1570255344 type Work @default.
- W1570255344 sameAs 1570255344 @default.
- W1570255344 citedByCount "5" @default.
- W1570255344 countsByYear W15702553442012 @default.
- W1570255344 crossrefType "journal-article" @default.
- W1570255344 hasAuthorship W1570255344A5057198789 @default.
- W1570255344 hasAuthorship W1570255344A5076390789 @default.
- W1570255344 hasConcept C113196181 @default.
- W1570255344 hasConcept C121332964 @default.
- W1570255344 hasConcept C127413603 @default.
- W1570255344 hasConcept C147789679 @default.
- W1570255344 hasConcept C150394285 @default.
- W1570255344 hasConcept C161790260 @default.
- W1570255344 hasConcept C172120300 @default.
- W1570255344 hasConcept C178790620 @default.
- W1570255344 hasConcept C179104552 @default.
- W1570255344 hasConcept C185592680 @default.
- W1570255344 hasConcept C192562407 @default.
- W1570255344 hasConcept C2776419971 @default.
- W1570255344 hasConcept C2776779347 @default.
- W1570255344 hasConcept C42360764 @default.
- W1570255344 hasConcept C43617362 @default.
- W1570255344 hasConcept C49110097 @default.
- W1570255344 hasConcept C504270822 @default.
- W1570255344 hasConcept C51038369 @default.
- W1570255344 hasConcept C512968161 @default.
- W1570255344 hasConcept C97355855 @default.
- W1570255344 hasConceptScore W1570255344C113196181 @default.
- W1570255344 hasConceptScore W1570255344C121332964 @default.
- W1570255344 hasConceptScore W1570255344C127413603 @default.
- W1570255344 hasConceptScore W1570255344C147789679 @default.
- W1570255344 hasConceptScore W1570255344C150394285 @default.
- W1570255344 hasConceptScore W1570255344C161790260 @default.
- W1570255344 hasConceptScore W1570255344C172120300 @default.
- W1570255344 hasConceptScore W1570255344C178790620 @default.
- W1570255344 hasConceptScore W1570255344C179104552 @default.
- W1570255344 hasConceptScore W1570255344C185592680 @default.
- W1570255344 hasConceptScore W1570255344C192562407 @default.
- W1570255344 hasConceptScore W1570255344C2776419971 @default.
- W1570255344 hasConceptScore W1570255344C2776779347 @default.
- W1570255344 hasConceptScore W1570255344C42360764 @default.
- W1570255344 hasConceptScore W1570255344C43617362 @default.
- W1570255344 hasConceptScore W1570255344C49110097 @default.
- W1570255344 hasConceptScore W1570255344C504270822 @default.
- W1570255344 hasConceptScore W1570255344C51038369 @default.
- W1570255344 hasConceptScore W1570255344C512968161 @default.
- W1570255344 hasConceptScore W1570255344C97355855 @default.
- W1570255344 hasIssue "10" @default.
- W1570255344 hasLocation W15702553441 @default.
- W1570255344 hasOpenAccess W1570255344 @default.
- W1570255344 hasPrimaryLocation W15702553441 @default.
- W1570255344 hasRelatedWork W1994291208 @default.
- W1570255344 hasRelatedWork W2003688997 @default.
- W1570255344 hasRelatedWork W2014564471 @default.
- W1570255344 hasRelatedWork W2015119765 @default.
- W1570255344 hasRelatedWork W2041360529 @default.
- W1570255344 hasRelatedWork W2081070655 @default.
- W1570255344 hasRelatedWork W2087419310 @default.
- W1570255344 hasRelatedWork W2407609834 @default.
- W1570255344 hasRelatedWork W2748952813 @default.
- W1570255344 hasRelatedWork W2899084033 @default.
- W1570255344 hasVolume "141" @default.
- W1570255344 isParatext "false" @default.
- W1570255344 isRetracted "false" @default.
- W1570255344 magId "1570255344" @default.
- W1570255344 workType "article" @default.