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• W1570323072 abstract "Abstract This chapter discusses diverse aurocarbons, organometallic species which in their simplest form, the first class, are composed of only carbon and gold: they may be understood as binary gold carbides, binary carbon aurides, and as hydrocarbons in which the hydrogens have been replaced by gold. Such species include the highly explosive solid C 2 Au 2 and gas phase exohedral gold‐fullerene complexes (C 60 )2Au + . The second class of aurocarbons are species of the first class in which ligands have been affixed to the gold atoms. This includes the stable C 2 Au 2 (P(C 6 H 5 ) 3 ) 2 and the octahedral [C(AuL) 6 ] 2+ (L = phenyl(bis(p‐tolyl)) phosphine, the latter isolable as the crystalline (BF 4 ) − salt. The third class allows for the presence of “a few” hydrogens or other univalent groups and so includes salts of the anion [HCCCCAuCCCCAuCCCCH] 2− and solutions of the cation [C 6 H 5 CC(AuP(C 6 H 5 ) 3 ) 2 ] + . It is to be emphasized that there must be direct gold–carbon bonding and so the heterometallic cluster Rh 10 C 2 (CO) 2 [AuP(C 6 H 5 ) 3 ) 4 ] is not an aurocarbon of any class even though it contains an allmetal polyhedron, ligated gold atoms, endohedral carbon atoms and a plethora of ligands." @default.
• W1570323072 created "2016-06-24" @default.
• W1570323072 creator A5008958784 @default.
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• W1570323072 date "2014-09-17" @default.
• W1570323072 modified "2023-10-18" @default.
• W1570323072 title "Aurocarbons: Binary Gold Carbides, Binary Carbon Aurides and their Derivatives" @default.
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• W1570323072 doi "https://doi.org/10.1002/9780470682531.pat0801" @default.
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