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• W1570341133 abstract "Abstract A complex of the composition [Bi(2‐OH‐C 6 H 4 CO 2 ) 3 (H 2 O)] ( 1 ) was isolated from the 1:3 reaction of BiPh 3 with H 2 sal (H 2 sal = salicylic acid = 2‐OH‐C 6 H 4 CO 2 H) in wet xylene, and the analogous anthranilate compound [Bi(2‐NH 2 ‐C 6 H 4 CO 2 ) 3 (H 2 O)] ( 2 ) was obtained from the 1:3 reaction of Bi(O t Bu) 3 with Hanth (Hanth = anthranilic acid = 2‐NH 2 ‐C 6 H 4 CO 2 H) in tetrahydrofuran. Compounds 1 and 2 were fully characterized spectroscopically and by single‐crystal X‐ray diffraction. Compounds 1 and 2 crystallize in the triclinic space group and display the η 2 ‐(O,O′) binding mode for the oxygen atoms of the carboxylate ligands. There are two independent molecules in the asymmetric units of 1 and 2 that are connected by a weak bridging interaction of the OH or NH 2 group to an adjacent molecule. Both bismuth atoms are bound to a H 2 O molecule, but the distances are highly asymmetric, long Bi ··· O lengths ranging from 2.74 to 2.89 Å." @default.
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• W1570341133 date "2015-01-15" @default.
• W1570341133 modified "2023-10-16" @default.
• W1570341133 title "The Unexpected Isolation of Bismuth Tris(carboxylate) Hydrates: Syntheses and Structures of [Bi(Hsal) ₃ (H ₂ O)] and [Bi(Hanth) ₃ (H ₂ O)] (H ₂ sal = 2‐OH‐C ₆ H ₄ CO ₂ H, Hanth = 2‐NH ₂ ‐C ₆ H ₄ CO ₂ H)" @default.
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• W1570341133 doi "https://doi.org/10.1002/ejic.201403019" @default.
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