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- W1570358452 abstract "The methoxylation of a-pinene was studied over sulfonic acid-functionalized mesoporous silica (MCM-41, PMO) at 60°C. The support functionalization was achieved by the introduction of 3-(mercaptopropyl)trimethoxysilane onto the surface of these materials either by grafting or by co-condensation. The thiol groups were oxidized to SO3H by treatment with H2O2. All the catalysts were active in the studied reaction being the PMO-SO3H-g the best one. Good values of selectivity to α-terpinyl methyl ether were obtained with these catalysts. Catalytic stability of the PMO-SO3H-g was evaluated by performing consecutive batch runs with the same catalyst sample. After the third batch it was observed a stabilisation of the activity." @default.
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- W1570358452 date "2008-01-01" @default.
- W1570358452 modified "2023-10-18" @default.
- W1570358452 title "Mesoporous silica containing sulfonic acid groups as catalysts for the alpha-pinene methoxylation" @default.
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- W1570358452 doi "https://doi.org/10.1016/s0167-2991(08)80132-2" @default.
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