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- W1570462462 abstract "Phase equilibrium curves of H2+ tetrahydrofuran and H2+ tetra-n-butyl ammonium bromide mixed gas hydrates were measured in a pressure range from 0.1 to 13.6 MPa. Each three-phase equilibrium curve converges at the maximum temperature point of pure tetrahydrofuran and tetra-n-butyl ammonium bromide hydrates, respectively. The difference of maximum temperatures is about 8 K, that is, the equilibrium curve of H2+ tetra-n-butyl ammonium bromide mixed gas hydrate shifts to the high-temperature side from that of H2+ tetrahydrofuran mixed gas hydrate. It is directly confirmed by use of Raman spectroscopy that H2 is enclathrated in the hydrate cages by adding a small amount of tetrahydrofuran or tetra-n-butyl ammonium bromide. In both mixed hydrates, H2 is enclathrated in only the small cage while tetrahydrofuran or tetra-n-butyl ammonium bromide occupies the large cages of each mixed hydrate." @default.
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- W1570462462 date "2006-12-01" @default.
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- W1570462462 title "Thermodynamic and Raman spectroscopic studies on <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML altimg=si15.gif display=inline overflow=scroll><mml:msub><mml:mrow><mml:mi mathvariant=normal>H</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub><mml:mo>+</mml:mo><mml:mi>tetrahydrofuran</mml:mi><mml:mo>+</mml:mo><mml:mi>water</mml:mi></mml:math> and <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML altimg=si16.gif display=inline overflow=scroll><mml…" @default.
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- W1570462462 doi "https://doi.org/10.1016/j.ces.2006.09.039" @default.
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