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• W1570480807 abstract "Methods for speciation measurements primarily involve the physical separation of species of interest from both the matrix and other forms of the same element and the subsequent analysis of the subsample. This approach generally assumes that species interconversion is negligible in the subsequent processing and analysis steps. Speciated isotope dilution mass spectrometry (SIDMS) is a measurement and diagnostic tool that addresses the correction of species transformation. SIDMS uses isotopes to “label” and trace species. This isotope dilution technique enables the quantitative correction of species transformation. In contrast to traditional methods that attempt to keep the species static, SIDMS permits the reactions that transform species to occur and corrects for these transformations. SIDMS can also correct for incomplete species separation and can be used as a diagnostic tool to evaluate other speciation methods. Isotope dilution mass spectrometry (IDMS) is specifically applied for measuring total elemental concentration and is based on the addition of a known amount of enriched isotope to a sample. Samples may need a variety of sample preparation procedures, depending on sample matrices and isotope ratio measurement methods." @default.
• W1570480807 created "2016-06-24" @default.
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• W1570480807 date "2000-01-01" @default.
• W1570480807 modified "2023-09-23" @default.
• W1570480807 title "Chapter 10 Application of isotope dilution in elemental speciation: speciated isotope dilution mass spectrometry (SIDMS)" @default.
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• W1570480807 doi "https://doi.org/10.1016/s0166-526x(00)80020-3" @default.
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