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• W1570491439 abstract "The review summarizes recent progress in the field of synthetic clay minerals pillared with organic or metal complex cations (PILCs). We briefly introduce the field of such PILCs and discuss the weaknesses of the state of the art characterization chart of PILCs. When PILCs are made from nanoscopic host materials like natural clay minerals, charge heterogeneity accompanied by interstratification, the turbostratic disorder in the stacking and the influence of the large external surface weaken essential analytical results. Turning to coarse-grained, well ordered clay minerals synthesized from the melt at temperatures above 1000 K removes all these obstacles and allows to present consistent data underlining the validity of the appealing pillaring concept: Refinement of PILC structures gives information on the pillar-host interaction and the orientation of pillars in the interlayer space. Two-dimensional superstructure reflections give direct evidence of the well-ordered lateral arrangement of pillars. And most importantly, analysis of chemical composition and physisorption isotherms are not corrupted by contributions of large external surfaces and this allows for predicting micropore volume and widths from pillar/host ratios in combination with pillar size/shape. Moreover, recent progress allows fine-tuning the charge density of the host lattice post-synthesis. Such deliberate and fine-graded alteration of the pillar density in turn permits adjusting the pore size in steps as small as 0.1 Å to a given adsorbate and thus will pave the way to maximize adsorption enthalpies and to improve selectivity. This feature is unique to PILCs and is not available to MOFs whose porosity can be adjusted only in steps no smaller than the order of chemical bond lengths. Rational design of microporous hybrid materials with full control over size, shape, and chemical nature of micropores certainly represents the strength and great potential of the pillaring approach." @default.
• W1570491439 created "2016-06-24" @default.
• W1570491439 creator A5069743496 @default.
• W1570491439 creator A5090008891 @default.
• W1570491439 date "2014-01-09" @default.
• W1570491439 modified "2023-09-25" @default.
• W1570491439 title "The Largely Unknown Class of Microporous Hybrid Materials: Clays Pillared by Molecules" @default.
• W1570491439 cites W1525826791 @default.
• W1570491439 cites W1652940835 @default.
• W1570491439 cites W194589484 @default.
• W1570491439 cites W1963858241 @default.
• W1570491439 cites W1964032123 @default.
• W1570491439 cites W1968882216 @default.
• W1570491439 cites W1974891260 @default.
• W1570491439 cites W1977632258 @default.
• W1570491439 cites W1979260051 @default.
• W1570491439 cites W1982987734 @default.
• W1570491439 cites W1983216715 @default.
• W1570491439 cites W1983279613 @default.
• W1570491439 cites W1986837259 @default.
• W1570491439 cites W1989579254 @default.
• W1570491439 cites W1992197068 @default.
• W1570491439 cites W1993000607 @default.
• W1570491439 cites W1994052174 @default.
• W1570491439 cites W1999908724 @default.
• W1570491439 cites W1999937609 @default.
• W1570491439 cites W2005175520 @default.
• W1570491439 cites W2012178448 @default.
• W1570491439 cites W2013307957 @default.
• W1570491439 cites W2014128072 @default.
• W1570491439 cites W2020249542 @default.
• W1570491439 cites W2021068733 @default.
• W1570491439 cites W2021134586 @default.
• W1570491439 cites W2025336678 @default.
• W1570491439 cites W2036056606 @default.
• W1570491439 cites W2042879497 @default.
• W1570491439 cites W2043979316 @default.
• W1570491439 cites W2051157204 @default.
• W1570491439 cites W2051409432 @default.
• W1570491439 cites W2066784839 @default.
• W1570491439 cites W2067442875 @default.
• W1570491439 cites W2068006175 @default.
• W1570491439 cites W2070625205 @default.
• W1570491439 cites W2073948920 @default.
• W1570491439 cites W2077814581 @default.
• W1570491439 cites W2086670878 @default.
• W1570491439 cites W2089892688 @default.
• W1570491439 cites W2093072861 @default.
• W1570491439 cites W2095730131 @default.
• W1570491439 cites W2099486431 @default.
• W1570491439 cites W2102932326 @default.
• W1570491439 cites W2103131973 @default.
• W1570491439 cites W2103829561 @default.
• W1570491439 cites W2105882551 @default.
• W1570491439 cites W2107644091 @default.
• W1570491439 cites W2107867222 @default.
• W1570491439 cites W2110993530 @default.
• W1570491439 cites W2115764422 @default.
• W1570491439 cites W2119640781 @default.
• W1570491439 cites W2122316263 @default.
• W1570491439 cites W2124359093 @default.
• W1570491439 cites W2127919073 @default.
• W1570491439 cites W2128405848 @default.
• W1570491439 cites W2134127132 @default.
• W1570491439 cites W2144071838 @default.
• W1570491439 cites W2148233016 @default.
• W1570491439 cites W2159363792 @default.
• W1570491439 cites W2159729153 @default.
• W1570491439 cites W2162846314 @default.
• W1570491439 cites W2166249115 @default.
• W1570491439 cites W2288897667 @default.
• W1570491439 cites W2321602552 @default.
• W1570491439 cites W2322505461 @default.
• W1570491439 cites W2322506930 @default.
• W1570491439 cites W2322723381 @default.
• W1570491439 cites W2327096520 @default.
• W1570491439 cites W2327294914 @default.
• W1570491439 cites W2327526941 @default.
• W1570491439 cites W2949405579 @default.
• W1570491439 cites W2950808674 @default.
• W1570491439 cites W2952491036 @default.
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• W1570491439 doi "https://doi.org/10.1002/zaac.201300540" @default.
• W1570491439 hasPublicationYear "2014" @default.
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