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• W1570567799 endingPage "096002" @default.
• W1570567799 startingPage "096002" @default.
• W1570567799 abstract "Magnetization and high resolution neutron powder diffraction measurements on the magnetic shape memory compound Ni2Mn1.48Sb0.52 have confirmed that it is ferromagnetic below 350 K and undergoes a structural phase transition at TM≈310 K. The high temperature phase has the cubic L21 structure with a = 5.958 Å, with the excess manganese atoms occupying the 4(b) Sb sites. In the cubic phase above ≈310 K the manganese moments are ferromagnetically aligned. The magnetic moment at the 4(a) site is 1.57(12) μB and it is almost zero (0.15(9) μB) at the 4(b) site. The low temperature orthorhombic phase which is only fully established below 50 K has the space group Pmma with a cell related to the cubic one by a Bain transformation aorth = (acub + bcub)/2; borth = ccub and corth = (acub − bcub). The change in cell volume is ≈2.5%. The spontaneous magnetization of samples cooled in fields less than 0.5 T decreases at temperatures below TM and at 2 K the magnetic moment per formula unit in fields up to 5.5 T is 2.01(5) μB. Neutron diffraction patterns obtained below ≈132 K gave evidence for a weak incommensurate magnetic modulation with propagation vector (2/3, 1/3, 0)." @default.
• W1570567799 created "2016-06-24" @default.
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• W1570567799 date "2010-02-10" @default.
• W1570567799 modified "2023-10-14" @default.
• W1570567799 title "Magnetic and structural properties of the magnetic shape memory compound Ni₂Mn_1.48Sb_0.52" @default.
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• W1570567799 doi "https://doi.org/10.1088/0953-8984/22/9/096002" @default.
• W1570567799 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21389429" @default.
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