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- W1570695416 abstract "Abstract The transient molecular flow of sorbable gases through a capillary has been treated mathematically: Corresponding to the delay of the outflowing process (“time lag”) the inflow of the gas is also affected by adsorption (“time lead”). The evaluation of adsorption isotherms from molecular flow experiments is described. Since the whole pressure range below the inlet pressure is covered during a single experiment studies of transient molecular flow are particularly suited for obtaining and characterizing adsorption isotherms at low surface coverages. The influence of the adsorption isotherm on the parameters of the transient flow — an initial delay and a stretch in time — is discussed. Conditions are specified, under which an eventual transition of a non-linear (e.g. Dubinin-Radushkevich-) to a Henry-isotherm could become apparent at extremely low surface coverages." @default.
- W1570695416 created "2016-06-24" @default.
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- W1570695416 date "1968-04-01" @default.
- W1570695416 modified "2023-10-14" @default.
- W1570695416 title "Adsorptionskinetik" @default.
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- W1570695416 doi "https://doi.org/10.1016/0039-6028(68)90083-6" @default.
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