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• W1570700812 abstract "The electrical conduction of a series of polycristalline [(1− x )CeO 2 ⋅ x /2Bi 2 O 3 ] samples has been analyzed using electrical impedance spectroscopy, in the temperature range 25 to<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:msup><mml:mrow><mml:mtext>750</mml:mtext></mml:mrow><mml:mo>∘</mml:mo></mml:msup></mml:mrow></mml:math>C. Samples have been prepared via a coprecipitation route followed by a pyrolysis process at<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:msup><mml:mrow><mml:mtext>600</mml:mtext></mml:mrow><mml:mo>∘</mml:mo></mml:msup></mml:mrow></mml:math>C. For compositions<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:mi>x</mml:mi><mml:mo>≤</mml:mo><mml:mn>0.20</mml:mn></mml:mrow></mml:math>, Ce 1− x Bi x O 2− x /2 solid solutions, with fluorite cubic structure, are obtained. In the composition range<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:mn>0.30</mml:mn><mml:mo>≤</mml:mo><mml:mi>x</mml:mi><mml:mo>≤</mml:mo><mml:mn>1</mml:mn></mml:mrow></mml:math>, the system is biphasic with coexistence of cubic and tetragonal structures. To interpret the Nyquist representations of electrical analyses, various impedance models including constant phase elements and Warburg impedances have been used. In the biphasic range (<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:mn>0.30</mml:mn><mml:mo>≤</mml:mo><mml:mi>x</mml:mi><mml:mo>≤</mml:mo><mml:mn>0.7</mml:mn></mml:mrow></mml:math>), the conductivity variation might be related to the increasing fraction of two tetragonal β ′ and β-Bi 2 O 3 phases. The stabilization of the tetragonal phase coexisting with substituted ceria close to composition<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:mi>x</mml:mi><mml:mo>=</mml:mo><mml:mn>0.7</mml:mn></mml:mrow></mml:math>is associated with a high conduction of the mix system CeO 2 -Bi 2 O 3 ." @default.
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• W1570700812 date "2012-01-01" @default.
• W1570700812 modified "2023-09-30" @default.
• W1570700812 title "Electrical Properties of a CeO₂-<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:msub><mml:mrow><mml:mtext>Bi</mml:mtext></mml:mrow><mml:mrow><mml:mn mathvariant=bold>2</mml:mn></mml:mrow></mml:msub><mml:msub><mml:mrow><mml:mtext>O</mml:mtext></mml:mrow><mml:mrow><mml:mn mathvariant=bold>3</mml:mn></mml:mrow></mml:msub></mml:math>Mix System Elaborated at 600°C" @default.
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• W1570700812 doi "https://doi.org/10.1155/2012/452383" @default.
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