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- W1570780094 abstract "Poly(peptide)-wrapped unsubstituted metalophthalocyanines (Mt-Pc's, Mt = Fe, Co) were synthesized by polycondensation of amphiphilic bifunctional active esters of amino acids (1 and 2), which form micellar or reversed micellar aggregates and solubilize Mt-Pc's. Though Mt-Pc's are insoluble in most organic solvents, the obtained poly(peptide)-wrapped Mt-Pc's are soluble in protic solvents such as formic acid, dichloroacetic acid, and trifluoroacetic acid. The wrapped Mt-Pc's are stable, and their leakage out of the poly(peptide)s is not observed. UV-Vis spectra revealed that the wrapped Fe-Pc is predominantly in the monomeric state. ESR spectra confirmed the poly(peptide)-wrapped structure of Mt-Pc's." @default.
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- W1570780094 date "1989-07-01" @default.
- W1570780094 modified "2023-09-27" @default.
- W1570780094 doi "https://doi.org/10.1002/macp.1989.021900718" @default.
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