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- W1570781152 abstract "用激光光解-激光诱导荧光方法研究了室温下（T=293K）NCF（~X^1A′）自由基与SO2分子的反应动力学．实验中HCF（~X^1A′）自由基是由213nm激光光解HCFBr2产生的，用激光诱导荧光（LIF）检测HCF（~X^1A′）自由基的相对浓度随着反应时间的变化，得到此反应的二级反应速率常数为：k=（1．81±0．15）×10^-12cm^3·molecule^-1·s^-1，体系总压为1862Pa．高精度理论计算表明，HCF（~X^1A′）和SO2分子反应的机理是典型的加成-消除反应．我们运用RRKM-TST理论计算了此二级反应速率常数的温度效应和压力效应，计算结果和室温下测定的二级反应速率常数符合得较好．" @default.
- W1570781152 created "2016-06-24" @default.
- W1570781152 creator A5036685113 @default.
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- W1570781152 creator A5080289760 @default.
- W1570781152 creator A5087992286 @default.
- W1570781152 date "2006-01-14" @default.
- W1570781152 modified "2023-09-22" @default.
- W1570781152 title "HCF(X~1A’)+SO2反应的动力学研究" @default.
- W1570781152 hasPublicationYear "2006" @default.
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