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- W1570785801 abstract "Fluoromethylglyoxal in the presence of glutathione has been shown to undergo a novel glyoxalase I-catalyzed product partitioning to S-fluorolactoylglutathione and S-pyruvylglutathione with fluoride elimination. While the partition ratio (fluoride eliminated/total fluoride) was insensitive to pH 5.5-7.5 and concentrations of substrate and glyoxalase I, it was species-dependent. When [1-2H]fluoromethylglyoxal was reacted with glyoxalase I, an increase in the partition ratio and retention of deuterium in the product fluorolactate was observed. This result can only be explained by a selective primary isotope effect on the protonation of an enediol intermediate relative to fluoride elimination." @default.
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- W1570785801 date "1981-10-01" @default.
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- W1570785801 title "Deuterium isotope effects on the product partitioning of fluoromethylglyoxal by glyoxalase I. Proof of a proton transfer mechanism." @default.
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- W1570785801 doi "https://doi.org/10.1016/s0021-9258(19)68690-4" @default.
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