FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W157079291> ?p ?o ?g. }

• W157079291 endingPage "411" @default.
• W157079291 startingPage "399" @default.
• W157079291 abstract "SummaryStarting with a discussion of the dependence of the activation energy of electron transport on reorganization energy, conclusions that apply to charge transfer in photosynthetic membrane proteins are: (i) a relatively low reorganization energy is anticipated from the low dielectric constant of the protein and membrane interior; (ii) the rate of intraprotein electron transfer in theory depends on the detailed pathway, but empirically a first-order rate-distance dependence for electron transfer holds over twelve orders of magnitude in rates, a factor of ten decrease for each 1.7 Å increase in center-center separation. Most of the data apply to the photosynthetic reaction center. (iii) The theories of the distance dependence of intraprotein electron transfer do not provide an explanation for the asymmetry of electron transfer, i.e., the far greater rate through the ‘L’ compared to the ‘M’ branch of the photosynthetic reaction center. (iv) The existence of long distance intraprotein electron transfer implies that the redox poise between centers separated by as much as 20 Å must be carefully regulated in vivo to avoid ‘promiscuous’ transfer events. (v) Special aspects of intramembrane electron transfer include (a) consideration of a three layer membrane model that includes a 10–15 Å thick interfacial layer of intermediate (ε=10–20) dielectric constant; and (b) in the case of the reaction center, a time-dependent ps→μs) increase in effective dielectric constant that is needed to keep the reaction activationless. (vi) Long distance transmembrane H+ translocation is likely to involve extended water chains, as inferred from recent atomic structure data on the n-side peripheral domain of the reaction center and the p-side peripheral domain of cytochrome f of the integral cytochrome b 6 f complex." @default.
• W157079291 created "2016-06-24" @default.
• W157079291 creator A5053504243 @default.
• W157079291 creator A5084692358 @default.
• W157079291 date "2005-12-30" @default.
• W157079291 modified "2023-09-27" @default.
• W157079291 title "Basic Aspects of Electron and Proton Transfer Reactions with Applications to Photosynthesis" @default.
• W157079291 cites W1486599573 @default.
• W157079291 cites W1505393044 @default.
• W157079291 cites W1533540035 @default.
• W157079291 cites W1674749902 @default.
• W157079291 cites W18007467 @default.
• W157079291 cites W1964554874 @default.
• W157079291 cites W1968842362 @default.
• W157079291 cites W1971332320 @default.
• W157079291 cites W1971499243 @default.
• W157079291 cites W1976155303 @default.
• W157079291 cites W1983318669 @default.
• W157079291 cites W1988812558 @default.
• W157079291 cites W1991979924 @default.
• W157079291 cites W1998864110 @default.
• W157079291 cites W2001270915 @default.
• W157079291 cites W2002484456 @default.
• W157079291 cites W2002793361 @default.
• W157079291 cites W2005602685 @default.
• W157079291 cites W2010274074 @default.
• W157079291 cites W2010669686 @default.
• W157079291 cites W2013001244 @default.
• W157079291 cites W2014400817 @default.
• W157079291 cites W2015940987 @default.
• W157079291 cites W2022409147 @default.
• W157079291 cites W2026074872 @default.
• W157079291 cites W2030139219 @default.
• W157079291 cites W2031904472 @default.
• W157079291 cites W2033764873 @default.
• W157079291 cites W2033804597 @default.
• W157079291 cites W2036374614 @default.
• W157079291 cites W2037111551 @default.
• W157079291 cites W2044626212 @default.
• W157079291 cites W2045120197 @default.
• W157079291 cites W2047549397 @default.
• W157079291 cites W2048541034 @default.
• W157079291 cites W2051397621 @default.
• W157079291 cites W2051568142 @default.
• W157079291 cites W2053316347 @default.
• W157079291 cites W2053839619 @default.
• W157079291 cites W2055975732 @default.
• W157079291 cites W2057270145 @default.
• W157079291 cites W2058552664 @default.
• W157079291 cites W2059745204 @default.
• W157079291 cites W2059929371 @default.
• W157079291 cites W2060065716 @default.
• W157079291 cites W2068806840 @default.
• W157079291 cites W2068910234 @default.
• W157079291 cites W2071030374 @default.
• W157079291 cites W2077055306 @default.
• W157079291 cites W2078537467 @default.
• W157079291 cites W2080868570 @default.
• W157079291 cites W2081295937 @default.
• W157079291 cites W2085719842 @default.
• W157079291 cites W2088103921 @default.
• W157079291 cites W2089680380 @default.
• W157079291 cites W2091237955 @default.
• W157079291 cites W2093973501 @default.
• W157079291 cites W2094795801 @default.
• W157079291 cites W2095216354 @default.
• W157079291 cites W2107244464 @default.
• W157079291 cites W2108453057 @default.
• W157079291 cites W2113475822 @default.
• W157079291 cites W2146686098 @default.
• W157079291 cites W2152013874 @default.
• W157079291 cites W2166305691 @default.
• W157079291 cites W2177024335 @default.
• W157079291 cites W2177451735 @default.
• W157079291 cites W2177655263 @default.
• W157079291 cites W2333931078 @default.
• W157079291 cites W2496151125 @default.
• W157079291 cites W4211025510 @default.
• W157079291 cites W4236221660 @default.
• W157079291 cites W4249116504 @default.
• W157079291 cites W83583953 @default.
• W157079291 doi "https://doi.org/10.1007/0-306-48127-8_20" @default.
• W157079291 hasPublicationYear "2005" @default.
• W157079291 type Work @default.
• W157079291 sameAs 157079291 @default.
• W157079291 citedByCount "0" @default.
• W157079291 crossrefType "book-chapter" @default.
• W157079291 hasAuthorship W157079291A5053504243 @default.
• W157079291 hasAuthorship W157079291A5084692358 @default.
• W157079291 hasConcept C121332964 @default.
• W157079291 hasConcept C123669783 @default.
• W157079291 hasConcept C147120987 @default.
• W157079291 hasConcept C148898269 @default.
• W157079291 hasConcept C159467904 @default.
• W157079291 hasConcept C179104552 @default.
• W157079291 hasConcept C184779094 @default.
• W157079291 hasConcept C185544564 @default.
• W157079291 hasConcept C185592680 @default.

• next