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- W1570842741 abstract "Abstract Thermodynamic experiments in electrosorption systems yield the electrosorption valency γ, the double-layer capacity CD and the maximum surface concentration Λmax as the most important results. These data are related to the geometric arrangement of the sorbate and its microscopic data, e.g. charge z, charge-transfer coefficient λ, dipole moment m, length l and area A of the molecule. Data are compiled and discussed for many aliphatic systems mainly on mercury and a few solid metal electrodes. For monosubstituted n-alkanes, the double-layer thickness is determined by l. Small positive values 0 Aliphatic ions have larger positive or negative γ-values depending on the charge sign. The geometric penetration of the functional group into the double layer is dominating. Charge transfer and, consequently, bond formation seem to be important for some sulfur-containing compounds only, such as thiourea and dibutylsulfide. Then negative γ-values are obtained with a negative coefficient dγ/dϵ, indicating the potential-dependent charge transfer λ. For thiourea on various metals, λ can be correlated to the formation enthalpies of the corresponding sulfides." @default.
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- W1570842741 date "1984-07-01" @default.
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- W1570842741 title "The electrosorption valency of organic electrosorbates" @default.
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- W1570842741 doi "https://doi.org/10.1016/0022-0728(84)80033-9" @default.
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