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- W1571296013 abstract "is one of the oxygen deficient ceramic materials widely investigated for both oxygen ion conduction and proton conduction in oxidizing atmospheres. However, its electrochemical properties have not been studied in hydrogen containing atmospheres. In this work, the electrical conductivity of in hydrogen containing atmospheres was investigated by ac impedance spectroscopy in the temperature range between 100 and and compared to its conductivity in air and nitrogen in order to estimate the contribution of proton conductivity to the total conductivity. A stable electrical conductivity of over was achieved in the temperature range of in a 50% vol vol atmosphere. Electromotive force measurements (and complimentary open circuit cell voltage measurements) revealed high proton transport numbers over the temperature range. shows chemical stability in hydrogen containing atmospheres at temperatures up to , while decomposing at higher temperatures. Mechanical instability was noticed in humid atmospheres at and above. This previously unreported high conductivity in atmosphere creates an opportunity for use of as a proton conductive material for a range of intermediate temperature electrochemical devices." @default.
- W1571296013 created "2016-06-24" @default.
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- W1571296013 date "2011-01-01" @default.
- W1571296013 modified "2023-10-01" @default.
- W1571296013 title "Proton Conductivity and Stability of Ba[sub 2]In[sub 2]O[sub 5] in Hydrogen Containing Atmospheres" @default.
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- W1571296013 doi "https://doi.org/10.1149/1.3511787" @default.
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