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• W1571927997 startingPage "5932" @default.
• W1571927997 abstract "Photolysis of [Cp*Re(CO)3] (Cp* = η5-C5Me5) with bromobenzene or chlorobenzene in benzene results in biphenyl and the corresponding rhenium hydride halide complex trans-[Cp*Re(CO)2H(X)], which further converts into the dihalide complexes cis/trans-[Cp*Re(CO)2X2] (X = Br, Cl). Additional experiments, including isotopic labeling experiments, indicate that one phenyl ring in biphenyl comes from the aryl halide and the other one comes from solvent benzene. Photolysis of [CpRe(CO)3] (Cp = η5-C5H5) with aryl halide in benzene similarly generates biphenyl, the corresponding rhenium hydride halide complex. Furthermore, the reaction also affords small amounts of rhenium dihydride complex [CpRe(CO)2H2]. Plausible mechanisms for the formation of the different types of products are proposed that involve intermolecular C–X and C–H activation. Molecular structures of trans-[Cp*Re(CO)2(Br)(Cl)] (trans-6) and trans-[CpRe(CO)2(Br)(Cl)] (trans-12) determined by X-ray diffraction are also presented." @default.
• W1571927997 created "2016-06-24" @default.
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• W1571927997 date "2014-10-30" @default.
• W1571927997 modified "2023-09-26" @default.
• W1571927997 title "Photochemical Reactions of [(η5-C5R5)Re(CO)3] (R = Me or H) with Aryl Halides in Benzene: Stoichiometric Formation of Biphenyl" @default.
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• W1571927997 doi "https://doi.org/10.1002/ejic.201402793" @default.
• W1571927997 hasPublicationYear "2014" @default.
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