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- W1572419617 abstract "The iron hexagonal mesoporous silica (Fe-HMS)-n photocatalyst, where n is the molar ratio Si/Fe in the precursor gel (=50), has been successfully synthesized at an ambient temperature using hexadecylamine as template agent. The material was characterized by X-ray diffraction, N2 adsorption measurement Brunauer, Emmet, Taller (BET) and Barrett–Joyner–Halenda theory, UV–Vis spectroscopy, high-resolution transmission electron microscopy and electron spin resonance. The electrical conductivity follows an Arrhenius-type law with activation energy of 0.04 eV. Fe2O3 is uniformly dispersed on the HMS surface; it works synergistically to make Fe-HMS photoelectrochemically active. The flat band potential (−0.75 VSCE) is higher than the potential of hydrogen generation (−0.50 VSCE at pH~7), and the material shows high efficiency for hydrogen evolution upon visible light. The photoactivity in Na2SO4 and Na2SO3 (0.1 M) solution was found to be 136 and 175 µmol g-1 min-1, respectively under full light (29 mW cm-2). The tendency to saturation, observed only in SO32- electrolyte, is ascribed to the competitive reduction of the end product, namely S2O62- with the water reduction. Copyright © 2011 John Wiley & Sons, Ltd." @default.
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- W1572419617 date "2011-07-06" @default.
- W1572419617 modified "2023-09-26" @default.
- W1572419617 title "Photo-induced hydrogen on iron hexagonal mesoporous silica (Fe-HMS) photo-catalyst" @default.
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- W1572419617 doi "https://doi.org/10.1002/er.1880" @default.
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