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• W1572528895 abstract "Luminescent metal organic frameworks (MOFs) are promising new materials with applications as sensors, photocatalysts, and other luminescent devices. Although MOFs retain the chemical and physical properties of their constituents, the properties of the MOF are often altered from those of its building blocks, making rational design and synthesis difficult.Anthracene is a polyaromatic hydrocarbon whose photophysical properties have been found to be easily tuned through structural modifications. The tunability of anthracene makes it an ideal candidate for use in luminescent devices, such as photoprobes and organic light emitting diodes. MOFs designed with π conjugated molecules like anthracene ligands possess similar photophysical properties such as absorption and fluorescence in the UV and visible spectrum. In hopes of better understanding how the photophysical properties of the organic ligand is altered upon incorporation into a MOF, the spectroscopic properties of anthracenedicarboxylic acids were studied before and after integration into zinc based MOFs.Steady state and time resolved measurements were performed on three anthracenedicarboxylic acids: 9,10-anthracenedicarboxylic acid, 2,6-anthracendicarboxylic acid, and 1,4-anthracenedicarboxylic acid. The position of the carboxylic acid groups on anthracene was found to effect the position and structure of the absorption and emission spectra. The difference in the spectra is attributed to the perturbation by the acid groups on certain electronic transitions with dipole moments across two of the three axes of anthracene. The position of the acid groups had different effects on the fluorescence quantum yields and lifetimes of the three anthracenic acids studied.Two of the linkers were synthesized into MOFs through a solvothermal reaction with zinc nitrate, to form PCN-13, from 9,10-anthracenedicarboxylic acid, and [Zn(C16H8O4)(H2O)]n, from 2,6-anthracenedicarboxylic acid. The luminescent properties of the two MOFs were studied and compared to those of the free based linker. Incorporation of the luminescent anthracenedicarboxylic acids into Zn based MOFs were found to either increase or decrease the luminescent properties of the ligands." @default.
• W1572528895 created "2016-06-24" @default.
• W1572528895 creator A5006999293 @default.
• W1572528895 date "2014-11-13" @default.
• W1572528895 modified "2023-09-23" @default.
• W1572528895 title "Photophysical Properties of Anthracenic Metal Organic Frameworks" @default.
• W1572528895 cites W1511064813 @default.
• W1572528895 cites W1551656287 @default.
• W1572528895 cites W1677747913 @default.
• W1572528895 cites W1963016962 @default.
• W1572528895 cites W1967413695 @default.
• W1572528895 cites W1967535708 @default.
• W1572528895 cites W1968127559 @default.
• W1572528895 cites W1971274408 @default.
• W1572528895 cites W1979487830 @default.
• W1572528895 cites W1980025402 @default.
• W1572528895 cites W1984614201 @default.
• W1572528895 cites W1985812386 @default.
• W1572528895 cites W1986931593 @default.
• W1572528895 cites W1987497788 @default.
• W1572528895 cites W1990036255 @default.
• W1572528895 cites W1990333918 @default.
• W1572528895 cites W1990918587 @default.
• W1572528895 cites W1993908005 @default.
• W1572528895 cites W1995754562 @default.
• W1572528895 cites W1997813480 @default.
• W1572528895 cites W1999460172 @default.
• W1572528895 cites W1999908724 @default.
• W1572528895 cites W2001877349 @default.
• W1572528895 cites W2002799357 @default.
• W1572528895 cites W2003969074 @default.
• W1572528895 cites W2006377435 @default.
• W1572528895 cites W2008568277 @default.
• W1572528895 cites W2010423349 @default.
• W1572528895 cites W2012530447 @default.
• W1572528895 cites W2014054292 @default.
• W1572528895 cites W2014138437 @default.
• W1572528895 cites W2015216092 @default.
• W1572528895 cites W2018303400 @default.
• W1572528895 cites W2021101301 @default.
• W1572528895 cites W2023271753 @default.
• W1572528895 cites W2023873504 @default.
• W1572528895 cites W2024689358 @default.
• W1572528895 cites W2024770896 @default.
• W1572528895 cites W2026605145 @default.
• W1572528895 cites W2026637041 @default.
• W1572528895 cites W2028258211 @default.
• W1572528895 cites W2028981084 @default.
• W1572528895 cites W2032231369 @default.
• W1572528895 cites W2032425101 @default.
• W1572528895 cites W2035498660 @default.
• W1572528895 cites W2036648677 @default.
• W1572528895 cites W2038440906 @default.
• W1572528895 cites W2042397184 @default.
• W1572528895 cites W2042509191 @default.
• W1572528895 cites W2044264692 @default.
• W1572528895 cites W2045021856 @default.
• W1572528895 cites W2047242736 @default.
• W1572528895 cites W2048428864 @default.
• W1572528895 cites W2051122541 @default.
• W1572528895 cites W2052388218 @default.
• W1572528895 cites W2052525123 @default.
• W1572528895 cites W2056127514 @default.
• W1572528895 cites W2056593708 @default.
• W1572528895 cites W2057331590 @default.
• W1572528895 cites W2058142269 @default.
• W1572528895 cites W2058910139 @default.
• W1572528895 cites W2060997968 @default.
• W1572528895 cites W2063368423 @default.
• W1572528895 cites W2063695253 @default.
• W1572528895 cites W2064073484 @default.
• W1572528895 cites W2066784675 @default.
• W1572528895 cites W2068486971 @default.
• W1572528895 cites W2068521044 @default.
• W1572528895 cites W2073529317 @default.
• W1572528895 cites W2075641866 @default.
• W1572528895 cites W2076523437 @default.
• W1572528895 cites W2077741286 @default.
• W1572528895 cites W2077803061 @default.
• W1572528895 cites W2078122806 @default.
• W1572528895 cites W2083555382 @default.
• W1572528895 cites W2084294292 @default.
• W1572528895 cites W2085011218 @default.
• W1572528895 cites W2087928781 @default.
• W1572528895 cites W2088694029 @default.
• W1572528895 cites W2090599463 @default.
• W1572528895 cites W2092023471 @default.
• W1572528895 cites W2092312531 @default.
• W1572528895 cites W2093599911 @default.
• W1572528895 cites W2099806401 @default.
• W1572528895 cites W2100620010 @default.
• W1572528895 cites W2102163049 @default.
• W1572528895 cites W2106577273 @default.
• W1572528895 cites W2106788928 @default.
• W1572528895 cites W2110157688 @default.
• W1572528895 cites W2114749728 @default.
• W1572528895 cites W2124772802 @default.
• W1572528895 cites W2127430211 @default.
• W1572528895 cites W2131350133 @default.
• W1572528895 cites W2134382193 @default.

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